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“Two cubes?” asks Corina Darold, the bartender at Cakes & Ale in Decatur, before she pours my glass of Pappy Van Winkle’s 23-Year Family Reserve. I nod. Water unlocks the aromas and flavors of bourbon, but I particularly like the way slowly melting ice awakens the character of this unusually mature whiskey. Drinking it is like lingering over a world-class pastry chef’s ace creation: Apple and toffee scuffle for taste-bud space with sneaky spice and vanilla. A flash of orange peel shimmers through each sip’s afterglow.